东南极拉斯曼丘陵镁铁质麻粒岩的变质作用演化   总被引：5，自引：4，他引：1  

周信  仝来喜  刘小汉  王彦斌  陈义兵 《岩石学报》2014,30(6):1731-1747

拉斯曼丘陵（Larsemann Hills）位于东南极普里兹构造带的中部,研究该区麻粒岩的变质作用演化对于理解普里兹带的构造属性至关重要。通过对该区含石榴石镁铁质麻粒岩转石详细的岩相学观察表明,峰期前进变质阶段矿物组合（M1）由角闪石+斜方辉石+单斜辉石+斜长石+黑云母+钛铁矿±石英±磁铁矿组成,其峰期矿物组合（M2）为石榴石+斜方辉石+单斜辉石+角闪石+钛铁矿±磁铁矿±石英,而代表后期与降压有关的叠加变质组合（M3）为斜方辉石+斜长石+单斜辉石+黑云母+钛铁矿±磁铁矿。矿物化学分析,结果显示其中石榴子石和斜方辉石具有弱的成分环带特征。利用THERMOCALC软件在NCFMASHTO体系下对该麻粒岩进行了详细的热力学模拟,结合传统温压计和平均温压计算结果,得出不同阶段温压条件分别为650~750℃/5.5~6.5kb （M1）,850~950℃/8~8.5kb （M2）,800~900℃/5.5~7.5kb （M3）。其变质作用演化为典型的峰期后近等温减压的（ITD）顺时针P-T轨迹。通过区域上镁铁质麻粒岩的对比分析,我们认为该镁铁质麻粒岩可能来源拉斯曼丘陵基岩露头。结合已有的年代学资料,表明该镁铁质麻粒岩的峰期变质事件可能对应于晚元古代格林威尔期构造事件,而后期退变质作用与早古生代的泛非期构造事件有关,意味着泛非期普里兹带可能是陆内造山带。  相似文献   

羟基磷灰石对水溶液中Fe³⁺的吸附动力学及热力学研究          下载免费PDF全文

周珍旭  钱功明  李道  王发杰 《岩石矿物学杂志》2014,33(6):1157-1160

研究了羟基磷灰石(HAP)对水溶液中Fe3+的吸附动力学及热力学。研究表明,HAP对水溶液中Fe3+的吸附符合Langmiur等温吸附,ct/q=0.006 4 ct+0.018 3;该吸附反应符合一级反应动力学方程,ln CR=-0.043 5 t+4.324 4;吸附反应活化能为Ea=36.26 k J/mol;标准摩尔反应焓为正值表明反应过程吸热;当温度大于285.7 K时,吉布斯自由能小于0,反应可自发进行。  相似文献   

The relationship between apparent equilibrium temperature and closure temperature with application to oxygen isotope geospeedometry     

Huaiwei Ni 《中国地球化学学报》2014,33(2):125-130

Oxygen isotope fractionation between coexisting minerals in slowly cooled rocks conveys information about their cooling history. By using the fast grain boundary （FGB） model to simulate closed-system diffusive ex- change of oxygen isotopes between coexisting minerals, I show that the apparent equilibrium temperatures （Tae） by the mineral pair with the largest isotopic fractionation （PLIF） always lies between the closure temperatures （To） of those two minerals. Therefore, when the rate of oxygen diffusion and hence Tc for the PLIF chance to be comparable （such as in the case of quartz and magnetite）, Tae will serve as a good approximation of To regardless of variation in mineral proportions. The specialty of the PLIF in constraining Tac within their Tc range can be generalized to other stable isotope systems and element partitioning. By approximating Tc with Tac and inverting Dodson＇s equation, the cooling rate of plutonic or metamorphic rocks can be inferred.  相似文献   

Phase Equilibria of Salt-water Systems Containing Magnesium and Borate Ions     

HAN Xunian  GUO Yafei  WANG Shiqiang  DENG Tianlong 《《地质学报》英文版》2014,88(Z1):331-332

正1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is  相似文献   

Studies on the Thermodynamics and Thermal Chemistry Properties for Lithium Salts and Their Aqueous Solution Systems     

LI Long  GAO Daolin  GUO Yafei  DENG Tianlong 《《地质学报》英文版》2014,88(Z1):345-346

正1 Introduction With the industrial development of lithium battery,nuclear and aerospace industry,the demands of metal lithium and its compounds are increasing significantly.Lithium is called as the energy of the metal in the new century(Zhang et al.2001).The total reserve of lithium resources around the world7  相似文献   

Gravitational collapse and equilibrium conditions of a toroidal vortex with thermal pressure     

K. Yu. Bliokh  V. M. Kontorovich 《Astronomy Letters》2003,29(11):724-730

We found the equilibrium conditions for a self-gravitating toroidal vortex by taking thermal pressure into account. These conditions are shown to significantly differ from those for a disk or a sphere. The evolution of a thin vortex turns it into a compact vortex that loses mechanical stability for low masses at a polytropic index γ<4/3 but retains stability for sufficiently high masses and densities determined by the velocity circulation in the vortex.  相似文献   

Thermodynamic modelling of the reaction muscovite+cordierite→Al₂SiO₅+biotite+quartz+ H₂O: constraints from natural assemblages and implications for the metapelitic petrogenetic grid     

D. R. M. Pattison  F. S. Spear  C. L. Debuhr  J. T. Cheney  C. V. Guidotti 《Journal of Metamorphic Geology》2002,20(1):99-118

The reaction muscovite+cordierite→biotite+Al₂SiO₅ +quartz+H₂O is of considerable importance in the low pressure metamorphism of pelitic rocks: (1) its operation is implied in the widespread assemblage Ms + Crd +And± Sil + Bt + Qtz, a common mineral assemblage in contact aureoles and low pressure regional terranes; (2) it is potentially an important equilibrium for pressure estimation in low pressure assemblages lacking garnet; and (3) it has been used to distinguish between clockwise and anticlockwise P–T paths in low pressure metamorphic settings. Experiments and thermodynamic databases provide conflicting constraints on the slope and position of the reaction, with most thermodynamic databases predicting a positive slope for the reaction. Evidence from mineral assemblages and microtextures from a large number of natural prograde sequences, in particular contact aureoles, is most consistent with a negative slope (andalusite and/or sillimanite occurs upgrade of, and may show evidence for replacement of, cordierite). Mineral compositional trends as a function of grade are variable but taken as a whole are more consistent with a negative slope than a positive slope. Thermodynamic modelling of reaction 1 and associated equilibria results in a low pressure metapelitic petrogenetic grid in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH) which satisfies most of the natural and experimental constraints. Contouring of the Fe–Mg divariant interval represented by reaction 1 allows for pressure estimation in garnet‐absent andalusite+cordierite‐bearing schists and hornfelses. The revised topology of reaction 1 allows for improved analysis of P–T paths from mineral assemblage sequences and microtextures in the same rocks.  相似文献   

Corrections to Solar Thermal Structure when a Turbulent Magnetic Field is Included     

Yi Liao  Shao-Lan BiNational Astronomical Observatories  Yunnan Observatory  Kunming   《中国天文和天体物理学报》2004,4(5):490-498

Correction of non-ideal effect due to a magnetic fluctuating tensor is derived from the ideal MHD equations. The inclusion of a magnetic turbulent field leads to modifications of the hydrostatic equilibrium equation and thermodynamical variables such as the temperature T, the adiabatic exponent γ, the adiabatic temperature gradient △↓ad and the temperature gradient △↓. In particular, the modifications in the adiabatic and radiative temperature gradients will result in a change in the Schwarzchild criterion, hence in the location of the base of the convective zone. Incorporating the modifications, we construct a modified thermodynamical equilibrium structure of the Sun.  相似文献   

渤海的海冰数值预报   总被引：33，自引：0，他引：33  

白珊  吴辉碇 《气象学报》1998,56(2):139-153

根据渤海气候和冰情特点,在已有海冰模式研究基础上,提出模拟海冰增长、消融和漂移的动力－热力学模式。模式冰厚分布由开阔水、平整冰和堆积冰三要素表示。该模式已与数值天气预报模式、大气边界层模式、潮流模式联结,并于１９９０年到１９９６年在国家海洋环境预报中心进行渤海和北黄海冰情预报。其数值预报产品包括冰厚、密度集、冰速、冰外缘线、冰脊参数、局地冰厚以及接近石油平台的冰漂移轨迹等,传送到国家海洋预报台和渤海石油公司等有关用户。为了客观评价模式和检验预报结果,在逐日预报后进行统计检验。本文概述渤海冰情、卫星遥感应用、冰模式及其预报结果和检验。  相似文献   

中尺度对流复合体的热力学特征分析   总被引：1，自引：0，他引：1  

康凤琴 《干旱气象》1998,(4)

用合成分析方法探讨ＭＣＣ热力学结构的演变规律,结果表明：ＭＣＣ整个生命史里,对流层中下部为正涡度区,２００ｈＰａ以上为负涡度区;发展时刻辐合区突然抬升;ＭＣＣ前期的垂直上升速度最大中心高度低于后期的;ＭＣＣ的高低空的冷心、中层暖心的温度结构在成熟期以后不明显  相似文献